I just started using painter a couple of months ago. I crossover between Painter and Photoshop now and like them both for different reasons. I have a few custom brushes I use, but for the most part I like the default hard edge brush set at low opacity in Photoshop. In Painter I like the oils and the blenders. Very cool stuff. Thanks for the comment.
I think this is my favorite of the ones you've posted, I really like the earthy tones you used, greyer and browner colors than before, it gives a real sense of atmosphere to the painting. I really love the way you did her expression and the subtle pose, she seems very sad and the emotion is strong.